Heterogeneous versus homogeneous electron transfer reactions at liquid–liquid interfaces: The wrong question?

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Hopping Across Interfaces : Heterogeneous Electron Transfer Dynamics

The Electrochemical Society Interface • Winter 2000 avid Grahame established double layer studies in the United States. At the time of his famous review1 in 1947, experimental work was limited to thermodynamic studies at liquid mercury. In 1997, Grahame’s pioneering work was honored by a symposium of The Electrochemical Society2, where three distinct advances over the last 50 years became appar...

متن کامل

On the theory of electron transfer reactions at semiconductorÕliquid interfaces. II. A free electron model

Electron transfer reactions at semiconductor/liquid interfaces are studied using the Fermi Golden rule and a free electron model for the semiconductor and the redox molecule. Bardeen’s method is adapted to calculate the coupling matrix element between the molecular and semiconductor electronic states where the effective electron mass in the semiconductor need not equal the actual electron mass....

متن کامل

On the theory of electron transfer reactions at semiconductor electrodeÕliquid interfaces

Electron transfer reaction rate constants at semiconductor/liquid interfaces are calculated using the Fermi Golden Rule and a tight-binding model for the semiconductors. The slab method and a z-transform method are employed in obtaining the electronic structures of semiconductors with surfaces and are compared. The maximum electron transfer rate constants at Si/viologen and InP/Me2Fc 1/0 interf...

متن کامل

Freestanding Ultrathin Nanoparticle Membranes Assembled at Transient LiquidLiquid Interfaces

(please note that in this context, we defi ne as membrane any freestanding thin layer, regardless of selective mass-transport properties). These approaches rely on the possibility of NPs to adsorb and pack into a dense network at an interface. This can occur if the free energy of the nanoparticles bound at the interface is lower than that of the NPs in either of the two phases. [ 38–40 ] The su...

متن کامل

Proton Transfer Controlled Reactions at Liquid-Liquid Interfaces

Aalto University, P.O. Box 11000, FI-00076 Aalto www.aalto.fi Author Pekka Peljo Name of the doctoral dissertation Proton Transfer Controlled Reactions at Liquid-Liquid Interfaces Publisher School of Chemical Technology Unit Department of Chemistry Series Aalto University publication series DOCTORAL DISSERTATIONS 39/2013 Field of research Physical Chemistry Manuscript submitted 10 December 2012...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of Electroanalytical Chemistry

سال: 2016

ISSN: 1572-6657

DOI: 10.1016/j.jelechem.2016.02.023